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中国和美国；洁净煤技术；现状；发展趋势；战略建议 1

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A mini review on chemical fixation of CO 2 : Absorption and catalytic conversion into cyclic carbonates

Weili DAI, Chaktong AU, Shenglian LUO, Shuangfeng YIN,

《化学科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 163-171 doi: 10.1007/s11705-009-0235-0

摘要： In this article, we present our research results on chemical fixation of CO using organobismuth compounds. We fabricated bismuth biphenoate complex, Zn-Mg-Al composite oxides, and SBA-15 or Al-SBA-15 immobilized hydroxyl ionic liquid for CO cycloaddition onto epoxides. The hypervalent bismuth compounds show good ability for association and dissociation with CO. The bismuth biphenolate complexes are catalytically effective for the cycloaddition reaction. The heterogeneous catalysts, viz. Zn-Mg-Al oxides and SBA-15 or Al-SBA-15 immobilized ionic liquid, are efficient for the synthesis of cyclic carbonate from CO and epoxide. It is found that the presence of a trace amount of water can improve the catalytic activity of the immobilized ionic liquid.

关键词： SBA-15     CO cycloaddition     Al-SBA-15 immobilized     CO     dissociation    

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Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 817-829 doi: 10.1007/s11705-022-2254-z

摘要： Amino acids are important nitrogen-containing chemicals that have a variety of applications. Currently, fermentation is the widely employed method to produce amino acids; however, the products are mostly limited to natural amino acids in the L-configuration. Catalytic synthesis is an alternative approach for the synthesis of amino acids with different types and configurations, where the use of renewable biomass-based feedstocks is highly attractive. To date, several lignocellulose and triacylglycerol-derived intermediates, typically α-keto acids and α-hydroxyl acids, have been transformed into amino acids via the amination reaction in the presence of additional nitrogen sources (i.e., NH3·H2O). Making full use of inherent nitrogen in biomass (i.e., chitin and protein) to produce amino acids avoids the use of extra nitrogen sources and meets the requirements of green chemistry, which is attracting increasing attention. In this review, we summarize different chemical-catalytic systems for the transformation of biomass to amino acids. An outlook on the challenges and opportunities for more effective production of amino acids from biomass by catalytic methods is provided.

关键词： biomass     amino acids     chitin     nitrogen-containing compounds     lignocellulose    

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Preparation of Ni/SiO catalyst in ionic liquids for hydrogenation

FAN Qingming, LIU Yingxin, ZHENG Yifan, YAN Wei

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 63-68 doi: 10.1007/s11705-008-0013-4

摘要： A series of silica supported nickel catalysts were prepared from nickel nitrate and tetraethyl orthosilicate by the sol-gel method with the imidazolium type ionic liquids as solvents. The catalysts were characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Their catalytic performances for the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde were investigated. The results show that the Ni/SiO catalyst prepared with 1-(2-hydroxyethyl)-3-methyl-imidazole tetrafluoroborate ionic liquid as solvent exhibits the highest catalytic activity for the reaction. Under the optimal conditions of catalyst dosage (based on the mass of cinnamaldehyde used) 10%, reaction pressure 2 MPa, temperature 373 K and reaction time 2 h, the conversion of cinnamaldehyde and the selectivity to hydrocinnamaldehyde can reach 97.6% and 98.8%, respectively.

关键词： dispersive     conversion     catalytic     2-hydroxyethyl     catalytic activity    

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Production of hydrogen from fossil fuel: A review

《能源前沿（英文）》 2023年 第17卷 第5期   页码 585-610 doi: 10.1007/s11708-023-0886-4

摘要： Production of hydrogen, one of the most promising alternative clean fuels, through catalytic conversion from fossil fuel is the most technically and economically feasible technology. Catalytic conversion of natural gas into hydrogen and carbon is thermodynamically favorable under atmospheric conditions. However, using noble metals as a catalyst is costly for hydrogen production, thus mandating non-noble metal-based catalysts such as Ni, Co, and Cu-based alloys. This paper reviews the various hydrogen production methods from fossil fuels through pyrolysis, partial oxidation, autothermal, and steam reforming, emphasizing the catalytic production of hydrogen via steam reforming of methane. The multicomponent catalysts composed of several non-noble materials have been summarized. Of the Ni, Co, and Cu-based catalysts investigated in the literature, Ni/Al2O3 catalyst is the most economical and performs best because it suppresses the coke formation on the catalyst. To avoid carbon emission, this method of hydrogen production from methane should be integrated with carbon capture, utilization, and storage (CCUS). Carbon capture can be accomplished by absorption, adsorption, and membrane separation processes. The remaining challenges, prospects, and future research and development directions are described.

关键词： methane     catalytic conversion     natural gas     hydrogen production     CCUS    

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A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities

ZHANG Fumin, GUO Maiping, GE Hanqing, WANG Jun

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 296-299 doi: 10.1007/s11705-007-0054-0

摘要： An environmentally benign method for the synthesis of heteropoly acids HPMoVO·HO (PMoV, = 1−3) was developed by the reaction of an aqueous slurry which contained stoichiometric amounts of MoO, VO and HPO. Characterization of the as-synthesized catalysts with inductively coupled plasma (ICP) elemental analysis, thermogravimetry (TG), X-ray diffraction (XRD) and infrared (IR) spectroscopy indicated that V ions substituted for Mo ions in Keggin-type phosphomolybdic acid. The as-synthesized samples were found to be an efficient catalyst for the hydroxylation of benzene which was carried out in a mixed solvent of acetonitrile and acetic acid with aqueous hydrogen peroxide as oxidant. PMoV exhibi ted the highest benzene conversion of 34.5% with phenol selectivity of 100%.

关键词： conversion     heteropoly     Characterization     efficient catalyst     Keggin-type phosphomolybdic    

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Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 372-376 doi: 10.1007/s11705-007-0067-8

摘要： The perovskite-type LaSrCoO supported on the mullite fiber porous ceramics was prepared by means of the impregnating method, and was then characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD); thus we can come to the conclusion that the perovskite-type composite oxidant can disperse on the surface of mullite fiber ceramics. The catalytic activity of the LaSrCoO for NO and CO was evaluated. The effect of the doped 0.1 wt-% PdCl on the catalytic activity of the perovskite-type LaSrCoO was also discussed. The results show that the conversion rates of NO and CO respectively reaches 74.5% and 99% at 601°C without doped Pd, and both reach 100% at 350°C with a little doped Pd.

关键词： porous     conversion     catalytic activity     electron microscopy     perovskite-type LaSrCoO    

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Low-temperature selective catalytic reduction of NO with NH based on MnO-CeO/ACFN

SHEN Boxiong, LIU Ting, SHI Zhanliang, SHI Jianwei, YANG Tingting, ZHAO Ning

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 325-329 doi: 10.1007/s11705-008-0053-9

摘要： MnO-CeO/ACFN were prepared by the impregnation method and used as catalyst for selective catalytic reduction of NO with NH at 80°C–150°C. The catalyst was characterized by N-BET, scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The fraction of the mesopore and the oxygen functional groups on the surface of activated carbon fiber (ACF) increased after the treatment with nitric acid, which was favorable to improve the catalytic activities of MnO-CeO/ACFN. The experimental results show that the conversion of NO is nearly 100% in the range 100°C–150°C under the optimal preparation conditions of MnO-CeO/ACFN. In addition, the effects of a series of performance parameters, including initial NH concentration, NO concentration and O concentration, on the conversion of NO were studied.

关键词： preparation     conversion     favorable     selective catalytic     MnO-CeO/ACFN    

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Selective catalytic reduction of NOx from exhaust of lean-burn engine over Ag-Al2O3/cordierite catalyst

LI Junhua, KANG Shoufang, FU Lixin, HAO Jiming

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 143-146 doi: 10.1007/s11783-007-0025-1

摘要： A highly effective Ag-AlO catalyst was prepared using the sol-gel method, and characterized by surface area using nitrogen adsorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. The catalyst performance was tested on a real lean-burn gasoline engine. Only unburned hydrocarbons and carbon monoxide in the exhaust were directly used as reductant (without any external reductant), the maximum NO conversion could only reach 40% at 450?C. When an external reductant, ethanol was added, the average NO conversion was greater than 60%. At exhaust gas temperature range of 350 500?C, the maximum NO conversion reached about 90%. CO and HC could be efficiently oxidized with Pt-AO oxidation catalyst placed at the end of SCR converter. However, NO conversion drastically decreased because of the oxidation of some intermediates to NO again. The possible reaction mechanism was proposed as two typical processes, nitration, and reduction in HC-SCR over Ag-AlO.

关键词： lean-burn gasoline     external reductant     nitrogen adsorption     conversion     catalyst performance    

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Catalytic cracking of endothermic fuels in coated tube reactor

LI Jia, ZOU Jijun, ZHANG Xiangwen, GUO Wei, MI Zhentao

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 181-185 doi: 10.1007/s11705-008-0032-1

摘要： Suspensoid of HZSM-5 or HY zeolites mixed with a self-made ceramic-like binder was coated on the inner wall of a tubular reactor by gas-aided fluid displacement technology. The coated zeolites were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The coating thickness is 10–20 ?m and the particle size of the zeolites is in the range of 1–5 ?m. In the coated reactor, cracking of endothermic fuels including -dodecane and aviation fuel RP-3 was carried out separately under supercritical conditions at 600°C and 625°C to investigate their heat sinks and conversion of catalytic reactions. For the reaction catalyzed by HY(25% mass fraction) coating, the heat sink capacity of -dodecane are 815.7 and 901.9 kJ/kg higher than that of the bare tube at 600°C and at 625°C, respectively. Conversion of -dodecane also increases from 42% to 60% at 600°C and from 66% to 80% at 625°C. The coated zeolite can significantly inhibit the carbon deposition during supercritical cracking reactions.

关键词： HZSM-5     self-made ceramic-like     gas-aided     Conversion     Suspensoid    

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Hydrogel photocatalysts for efficient energy conversion and environmental treatment

《能源前沿（英文）》 2021年 第15卷 第3期   页码 577-595 doi: 10.1007/s11708-021-0756-x

摘要： Photocatalysts have attracted great research interest owing to their excellent properties and potential for simultaneously addressing challenges related to energy needs and environmental pollution. Photocatalytic particles need to be in contact with their respective media to exhibit efficient photocatalytic performances. However, it is difficult to separate nanometer-sized photocatalytic materials from reaction media later, which may lead to secondary pollution and a poor recycling performance. Hydrogel photocatalysts with a three-dimensional (3D) network structures are promising support materials for photocatalysts based on features such as high specific surface areas and adsorption capacities and good environmental compatibility. In this review, hydrogel photocatalysts are classified into two different categories depending on their elemental composition and recent progresses in the methods for preparing hydrogel photocatalysts are summarized. Moreover, current applications of hydrogel photocatalysts in energy conversion and environmental remediation are reviewed. Furthermore, a comprehensive outlook and highlight future challenges in the development of hydrogel photocatalysts are presented.

关键词： hydrogel     photocatalysts     energy conversion     environmental treatment    

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Biological conversion pathways of sulfate reduction ammonium oxidation in anammox consortia

Zhen Bi, Deqing Wanyan, Xiang Li, Yong Huang

《环境科学与工程前沿（英文）》 2020年 第14卷 第3期 doi: 10.1007/s11783-019-1217-1

摘要： The SRAO phenomena tended to occur only under certain conditions. High amount of biomass and non-anaerobic condition is requirement for SRAO. Anammox bacteria cannot oxidize ammonium with sulfate as electron acceptor. AOB and AnAOB are mainly responsible for ammonium conversion. Heterotrophic sulfate reduction mainly contributed to sulfate conversion. For over two decades, sulfate reduction with ammonium oxidation (SRAO) had been reported from laboratory experiments. SRAO was considered an autotrophic process mediated by anammox bacteria, in which ammonium as electron donor was oxidized by the electron acceptor sulfate. This process had been attributed to observed transformations of nitrogenous and sulfurous compounds in natural environments. Results obtained differed largely for the conversion mole ratios (ammonium/sulfate), and even the intermediate and final products of sulfate reduction. Thus, the hypothesis of biological conversion pathways of ammonium and sulfate in anammox consortia is implausible. In this study, continuous reactor experiments (with working volume of 3.8L) and batch tests were conducted under normal anaerobic (0.2≤DO<0.5 mg/L) / strict anaerobic (DO<0.2 mg/L) conditions with different biomass proportions to verify the SRAO phenomena and identify possible pathways behind substrate conversion. Key findings were that SRAO occurred only in cases of high amounts of inoculant biomass under normal anaerobic condition, while absent under strict anaerobic conditions for same anammox consortia. Mass balance and stoichiometry were checked based on experimental results and the thermodynamics proposed by previous studies were critically discussed. Thus anammox bacteria do not possess the ability to oxidize ammonium with sulfate as electron acceptor and the assumed SRAO could, in fact, be a combination of aerobic ammonium oxidation, anammox and heterotrophic sulfate reduction processes.

关键词： Anammox bacteria     Autotrophic     Biological conversion     Sulfate reducing ammonium oxidation (SRAO)    

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Sustainable conversion regenerated cellulose into cellulose oleate by sonochemistry

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1096-1108 doi: 10.1007/s11705-023-2317-9

摘要： Derivatization has great potential for the high-value utilization of cellulose by enhancing its processability and functionality. However, due to the low reactivity of natural cellulose, it remains challenging to rapidly prepare cellulose derivatives with high degrees of substitution. The “cavitation effect” of ultrasound can reduce the particle size and crystalline index of cellulose, which provides a possible method for preparing cellulose derivatives. Herein, a feasible method was proposed for efficiently converting regenerated cellulose to cellulose oleate with the assistance of ultrasonic treatment. By adjusting the reaction conditions including ultrasonic intensity, feeding ratios of oleic acid, reaction time, and reaction solvent, a series of cellulose oleates with degrees of substitution ranging from 0.37 to 1.71 were synthesized. Additionally, the effects of different reaction conditions on the chemical structures, crystalline structures, and thermal behaviors were investigated thoroughly. Cellulose oleates with degrees of substitution exceeding 1.23 exhibited amorphous structures and thermoplasticity with glass transition temperatures at 159.8 to 172.6 °C. This study presented a sustainable and practicable method for effectively derivatizing cellulose.

关键词： regenerated cellulose     cellulose oleate     sonochemistry     degree of substitution     thermoplasticity    

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A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第1期   页码 4-17 doi: 10.1007/s11705-020-1933-x

摘要： This review article summarizes the key published research on the topic of bio-oil upgrading using catalytic and non-catalytic supercritical fluid (SCF) conditions. The precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oil upgrading in SCFs. This is reportedly due to their favourable catalytic activity during the process including hydrotreating, hydrocracking, and esterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oil. Due to the costs associated with precious metal catalysts, some researchers have opted for non-precious metal catalysts such as acidic HZSM-5 which can promote esterification in supercritical ethanol. On the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst. Supercritical methanol, ethanol, and water are most commonly used and demonstrate catalyst like activities such as facilitating esterification reactions and reducing solid yield by alcoholysis and hydrolysis, respectively.

关键词： bio-oil     upgrading     supercritical     review    

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Dynamic contribution of variable-speed wind energy conversion system in system frequency regulation

Yajvender Pal VERMA, Ashwani KUMAR

《能源前沿（英文）》 2012年 第6卷 第2期   页码 184-192 doi: 10.1007/s11708-012-0185-y

摘要： Frequency regulation in a generation mix having large wind power penetration is a critical issue, as wind units isolate from the grid during disturbances with advanced power electronics controllers and reduce equivalent system inertia. Thus, it is important that wind turbines also contribute to system frequency control. This paper examines the dynamic contribution of doubly fed induction generator (DFIG)-based wind turbine in system frequency regulation. The modified inertial support scheme is proposed which helps the DFIG to provide the short term transient active power support to the grid during transients and arrests the fall in frequency. The frequency deviation is considered by the controller to provide the inertial control. An additional reference power output is used which helps the DFIG to release kinetic energy stored in rotating masses of the turbine. The optimal speed control parameters have been used for the DFIG to increases its participation in frequency control. The simulations carried out in a two-area interconnected power system demonstrate the contribution of the DFIG in load frequency control.

关键词： doubly fed induction generator (DFIG)     load frequency control     inertial control     wind energy conversion system (WECS)    

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标题 作者 时间 类型 操作

A mini review on chemical fixation of CO 2 : Absorption and catalytic conversion into cyclic carbonates

Weili DAI, Chaktong AU, Shenglian LUO, Shuangfeng YIN,

期刊论文

Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

期刊论文

Preparation of Ni/SiO catalyst in ionic liquids for hydrogenation

FAN Qingming, LIU Yingxin, ZHENG Yifan, YAN Wei

期刊论文

Production of hydrogen from fossil fuel: A review

期刊论文

A new method for the synthesis of molybdovanadophosphoric heteropoly acids and their catalytic activities

ZHANG Fumin, GUO Maiping, GE Hanqing, WANG Jun

期刊论文

Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

期刊论文

Low-temperature selective catalytic reduction of NO with NH based on MnO-CeO/ACFN

SHEN Boxiong, LIU Ting, SHI Zhanliang, SHI Jianwei, YANG Tingting, ZHAO Ning

期刊论文

Selective catalytic reduction of NOx from exhaust of lean-burn engine over Ag-Al2O3/cordierite catalyst

LI Junhua, KANG Shoufang, FU Lixin, HAO Jiming

期刊论文

Catalytic cracking of endothermic fuels in coated tube reactor

LI Jia, ZOU Jijun, ZHANG Xiangwen, GUO Wei, MI Zhentao

期刊论文

Hydrogel photocatalysts for efficient energy conversion and environmental treatment

期刊论文

Biological conversion pathways of sulfate reduction ammonium oxidation in anammox consortia

Zhen Bi, Deqing Wanyan, Xiang Li, Yong Huang

期刊论文

杨为民：石油化工CO2减排与转化中的催化技术（2021年5月21日）

2021年12月01日

会议视频

Sustainable conversion regenerated cellulose into cellulose oleate by sonochemistry

期刊论文

A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

期刊论文

Dynamic contribution of variable-speed wind energy conversion system in system frequency regulation

Yajvender Pal VERMA, Ashwani KUMAR

期刊论文